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Impedance spectroscopy analysis of pure and Ni-doped lithium tantalate

Identifieur interne : 000A44 ( Main/Exploration ); précédent : 000A43; suivant : 000A45

Impedance spectroscopy analysis of pure and Ni-doped lithium tantalate

Auteurs : F. Bennani [France] ; E. Husson [France]

Source :

RBID : ISTEX:0B2430EB8561F7857DB3EDC1DFCA545906CAD0D7

Abstract

Ceramics of LiTaO3 with different Li/Ta ratios and Li0.98−xTa1.004−x/5NixO3 solid solutions with 0⩽x⩽0.20 are studied by impedance spectroscopy in the 1 Hz–1 MHz frequency range and the 500–1200 K temperature range. The evolution of the dielectric properties and the Curie temperature are studied as a function of the Li/Ta ratio and of the Ni content. The ionic conductivity is determined for all compositions from Cole–Cole diagrams and the evolution vs temperature is studied as a function of the Li/Ta ratio and of the Ni content. The results are discussed and related to the substitution mechanism.

Url:
DOI: 10.1016/S0955-2219(00)00285-5


Affiliations:


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